| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | Christopher Pastor Ngaiza | Ambassador | 1965 – 1968 |
| 2 | Anthony Balthazar Nyaki | Ambassador | 1968 – 1970 |
| 3 | Idriss Abdul Wakil | Ambassador | 1970 – 1973 |
| 4 | Mahmoud Nasser Rattansey | Ambassador | 1973 – 1979 |
| 5 | Sebastian Chale | Ambassador | 1979 – 1984 |
| 6 | Sefania Tunginie | Ambassador | 1984 – 1989 |
| 7 | Seif Ali Iddi | Ambassador | 1989 – 1993 |
| 8 | Magnus Asterius Hyera | Ambassador | 1993 – 1994 |
| 9 | Diodorus Kamala | Acting Ambassador | 2012 – 2015 |
| 10 | Ufrosia Mlay | Acting Ambassador | 2002 – 2012 |
| 11 | Ali Karume | Acting Ambassador | 1995 – 2002 |
| 12 | Abdul Mshangama | Acting Ambassador | 1990 – 1995 |
| 13 | Wilson Mutagaywa Kajumula Masilingi | Ambassador | 2013 – 2015 |
